Issue 10, 2009
From the journal:

Dalton Transactions

Reactions of a hydrido(hydrosilylene)ruthenium complex with carbonyl compounds†

Mitsuyoshi Ochiai,a   Hisako Hashimoto*a  and  Hiromi Tobita*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Tohoku University, Aoba-ku, Sendai, Japan
E-mail: hhashimoto@mail.tains.tohoku.ac.jp, tobita@mail.tains.tohoku.ac.jp
Fax: +81 22 795 6543
Tel: +81 22 795 6541

Abstract

Reactions of a neutral silyleneruthenium complex with ketones and aldehydes, and isolation of their agostic intermediates are reported, where an α-H abstraction or hydrosilylation of the carbonyl compounds occurs depending on the substituents of the substrates.

Graphical abstract: Reactions of a hydrido(hydrosilylene)ruthenium complex with carbonyl compounds

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Article information

DOI
https://doi.org/10.1039/B819229B
Article type
Paper
Submitted
29 Oct 2008
Accepted
19 Nov 2008
First published
27 Jan 2009

Dalton Trans., 2009, 1812-1814

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Reactions of a hydrido(hydrosilylene)ruthenium complex with carbonyl compounds

M. Ochiai, H. Hashimoto and H. Tobita, Dalton Trans., 2009, 1812 DOI: 10.1039/B819229B

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