Water activation by SO2˙+ ions: an effective source of OH˙ radicals

Giulia de Petris; Antonella Cartoni; Anna Troiani; Giancarlo Angelini; Ornella Ursini

doi:10.1039/B915123K

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Wateractivation by SO₂˙⁺ ions: an effective source of OH˙ radicals

Giulia de Petris,*^a Antonella Cartoni,^a Anna Troiani,^a Giancarlo Angelini^b and Ornella Ursini^b

Author affiliations

* Corresponding authors

^a Dipartimento di Chimica e Tecnologie del Farmaco, Università“La Sapienza”, P.le Aldo Moro 5, 00185 Roma, Italy
E-mail: giulia.depetris@uniroma1.it

^b Istituto di Metodologie Chimiche, Area della Ricerca di Roma del CNR, CP 10, 00016 Monterotondo Stazione (RM), Italy

Abstract

A novel O–H bond activation reaction is reported: thermal SO₂˙⁺ radical cations activate water in the gas phase forming OH˙ radicals with 100% efficiency.

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Article information

DOI: https://doi.org/10.1039/B915123K
Article type: Communication
Submitted: 27 Jul 2009
Accepted: 03 Sep 2009
First published: 11 Sep 2009

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Phys. Chem. Chem. Phys., 2009,11, 9976-9978

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Water activation by SO₂˙⁺ ions: an effective source of OH˙ radicals

G. de Petris, A. Cartoni, A. Troiani, G. Angelini and O. Ursini, Phys. Chem. Chem. Phys., 2009, 11, 9976 DOI: 10.1039/B915123K

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