Issue 3, 2009
From the journal:

CrystEngComm

Structural similarities of 2-chlorophenol and 2-methylphenol†

Iain D. H. Oswald*ab  and  Wilson A. Crichtonb  

* Corresponding authors

a School of Chemistry and Centre for Science at Extreme Conditions, University of Edinburgh, Kings Buildings, West Mains Road, Edinburgh, UK
E-mail: iain.oswald@ed.ac.uk
Fax: +44 131 651 7049
Tel: +44 131651 7222

b European Synchrotron Radiation Facility, 6 Rue Jules Horowitz, BP 220, Grenoble Cedex 9, France

Abstract

Investigation of 2-methylphenol and 2-chlorophenol reveals similarities in structure at both low temperature and high pressure. Co-crystallisation of the two components results in the formation of a 0.45 : 0.55 2-methylphenol : 2-chlorophenol co-crystal at low temperature but at high pressure the mixture is separated resulting in the formation of a new polymorph of 2-chlorophenol.

Graphical abstract: Structural similarities of 2-chlorophenol and 2-methylphenol

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Article information

DOI
https://doi.org/10.1039/B813878H
Article type
Paper
Submitted
11 Aug 2008
Accepted
24 Sep 2008
First published
14 Oct 2008

CrystEngComm, 2009,11, 463-469

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Structural similarities of 2-chlorophenol and 2-methylphenol

I. D. H. Oswald and W. A. Crichton, CrystEngComm, 2009, 11, 463 DOI: 10.1039/B813878H

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