Issue 41, 2009
From the journal:

Chemical Communications

Highly enantioselective intramolecular aza-spiroannulation onto indoles using chiral rhodium catalysis: asymmetric entry to the spiro-β-lactam core of chartellines†

Shigeki Sato,a   Masatoshi Shibuya,a   Naoki Kanoha  and  Yoshiharu Iwabuchi*a  

* Corresponding authors

a Department of Organic Chemistry, Graduate School of Pharmaceutical Sciences, Tohoku University, 6-3Aobayama, Sendai 980-8578, Japan
E-mail: iwabuchi@mail.pharm.tohoku.ac.jp
Fax: +81-22-795-6845
Tel: +81-22-795-6846

Abstract

A versatile, highly enantiocontrolled entry to the spiro-β-lactam core of chartellines has been developed by expanding the scope of oxidative nitrogen atom transfer methodology based on chiral Rh-nitrenoid species.

Graphical abstract: Highly enantioselective intramolecular aza-spiroannulation onto indoles using chiral rhodium catalysis: asymmetric entry to the spiro-β-lactam core of chartellines

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Article information

DOI
https://doi.org/10.1039/B913770J
Article type
Communication
Submitted
09 Jul 2009
Accepted
13 Aug 2009
First published
02 Sep 2009

Chem. Commun., 2009, 6264-6266

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Highly enantioselective intramolecular aza-spiroannulation onto indoles using chiral rhodium catalysis: asymmetric entry to the spiro-β-lactam core of chartellines

S. Sato, M. Shibuya, N. Kanoh and Y. Iwabuchi, Chem. Commun., 2009, 6264 DOI: 10.1039/B913770J

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