How intimate contact with nanoporous carbon benefits the reversible hydrogen desorption from NaH and NaAlH4

Philipp Adelhelm; Krijn P. de Jong; Petra E. de Jongh

doi:10.1039/B910461E

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How intimate contact with nanoporous carbon benefits the reversible hydrogen desorption from NaH and NaAlH₄†

Philipp Adelhelm,^a Krijn P. de Jong^a and Petra E. de Jongh*^a

Author affiliations

* Corresponding authors

^a Inorganic Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Utrecht University, Sorbonnelaan 16, 3584 CA Utrecht, The Netherlands
E-mail: p.e.dejongh@uu.nl
Fax: +31 30 251 1027
Tel: +31 30 253 7400

Abstract

The kinetics and thermodynamics for the reversible hydrogen desorption from NaH (and NaH derived from NaAlH₄) are greatly improved by nanosizing and providing close contact to a porous carbon matrix.

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Supplementary files

Porosity measurements, dehydrogenation behavior of LiH/carboncomposite, cycling of 33NaH/C under H₂ atmosphere, experimental details PDF (373K)

Article information

DOI: https://doi.org/10.1039/B910461E
Article type: Communication
Submitted: 28 May 2009
Accepted: 14 Aug 2009
First published: 28 Aug 2009

Download Citation

Chem. Commun., 2009, 6261-6263

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How intimate contact with nanoporous carbon benefits the reversible hydrogen desorption from NaH and NaAlH₄

P. Adelhelm, K. P. de Jong and P. E. de Jongh, Chem. Commun., 2009, 6261 DOI: 10.1039/B910461E

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