Issue 44, 2009
From the journal:

Chemical Communications

Origin of the asymmetric induction in metallosalen-catalyzed reactions of aldehydes†

Wojciech Chaładaja  and  Janusz Jurczak*ab  

* Corresponding authors

a Institute of Organic Chemistry, Polish Academy of Sciences, 01-224 Warsaw, Poland
E-mail: jurczak@icho.edu.pl
Fax: +48 22 632 66 81
Tel: +48 22 343 23 30

b Department of Chemistry, Warsaw University, 02-093 Warsaw, Poland

Abstract

This study investigates, experimentally and computationally, the role played by the structure of the diamine moiety of salen chromium complexes in determining the catalyst conformational equilibrium and, in consequence, the direction of asymmetric induction in metallosalen-catalyzed reactions of aldehydes.

Graphical abstract: Origin of the asymmetric induction in metallosalen-catalyzed reactions of aldehydes

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Article information

DOI
https://doi.org/10.1039/B910473A
Article type
Communication
Submitted
28 May 2009
Accepted
17 Sep 2009
First published
07 Oct 2009

Chem. Commun., 2009, 6747-6749

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Origin of the asymmetric induction in metallosalen-catalyzed reactions of aldehydes

W. Chaładaj and J. Jurczak, Chem. Commun., 2009, 6747 DOI: 10.1039/B910473A

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