Issue 25, 2009

The oxidation of Ni(ii) N-confused porphyrins (NCPs) with azo radical initiators and an unexpected intramolecular nucleophilic substitution reactionvia a proposed Ni(iii) NCP intermediate

Abstract

The oxidation of Ni(II) N-confused porphyrins (NCPs) with azo radical initiators resulted in an unexpected intramolecular nucleophilic substitution reactionvia a proposed Ni(III) NCP intermediate, which could be detected by HRMS.

Graphical abstract: The oxidation of Ni(ii) N-confused porphyrins (NCPs) with azo radical initiators and an unexpected intramolecular nucleophilic substitution reactionvia a proposed Ni(iii) NCP intermediate

Supplementary files

Article information

Article type
Communication
Submitted
05 Mar 2009
Accepted
27 Apr 2009
First published
15 May 2009

Chem. Commun., 2009, 3732-3734

The oxidation of Ni(II) N-confused porphyrins (NCPs) with azo radical initiators and an unexpected intramolecular nucleophilic substitution reactionvia a proposed Ni(III) NCP intermediate

H. Jiang, Q. Chen, J. Xiao and Y. Gu, Chem. Commun., 2009, 3732 DOI: 10.1039/B904615A

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