Luminescence from cerium(iii) acetate complexes in aqueous solution: considerations on the nature of carboxylate binding to trivalent lanthanides
Abstract
The luminescence of cerium(III) has been studied in aqueous solutions in the presence of acetate ion. In contrast to previous reports that cerium(III) carboxylate complexes do not luminesce, a weak emission is observed, which has a similar spectrum to the aquo cerium(III) species but a much shorter lifetime. Results from a variety of studies on complexation of various trivalent lanthanide ions with carboxylates, including