Generation of cationic indenyl silylamide gadolinium and scandium complexes [(Ind)Ln{N(SiMe3)2}]+[B(C6F5)4]− and their reactivity for 1,3-butadiene polymerization

Abstract

Highly efficient cis-polymerization of butadiene was achieved by using new bis(indenyl) silylamide rare earth complexes with the cooperation of both a borate salt and i-Bu₃Al; treatment of these complexes with organoboron compounds unexpectedly yielded new cationic mono(indenyl) amido species relevant to polymerization.