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Issue 39, 2008
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Metal-catalyzed reaction of N-(2-indolyl)methyl, N-bis(trimethylsilyl)methyl diazoamides: an entry into the β-carboline ring system

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Abstract

The intramolecular metal-catalyzed reaction of N-(2-indolyl)methyl, N-bis(TMS)methyl diazoamides proceeds with high conformational control and chemoselectivity to give cyclopropyl derivatives, which rearrange to β-carboline products.

Graphical abstract: Metal-catalyzed reaction of N-(2-indolyl)methyl, N-bis(trimethylsilyl)methyl diazoamides: an entry into the β-carboline ring system

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Publication details

The article was received on 11 Jun 2008, accepted on 11 Jul 2008 and first published on 28 Aug 2008


Article type: Communication
DOI: 10.1039/B809890E
Citation: Chem. Commun., 2008,0, 4837-4839

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    Metal-catalyzed reaction of N-(2-indolyl)methyl, N-bis(trimethylsilyl)methyl diazoamides: an entry into the β-carboline ring system

    B. Zhang and A. G. H. Wee, Chem. Commun., 2008, 0, 4837
    DOI: 10.1039/B809890E

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