Cycloaddition reactions of transition metal hydrazides with alkynes and heteroalkynes: coupling of TiNNPh2 with PhCCMe, PhCCH, MeCN and tBuCP

Jonathan D. Selby; Christian Schulten; Andrew D. Schwarz; Andreas Stasch; Eric Clot; Cameron Jones; Philip Mountford

doi:10.1039/B813911C

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Cycloaddition reactions of transition metal hydrazides with alkynes and heteroalkynes: coupling of TiNNPh₂ with PhCCMe, PhCCH, MeCN and ^tBuCP†

Jonathan D. Selby,^a Christian Schulten,^b Andrew D. Schwarz,^a Andreas Stasch,^b Eric Clot,*^c Cameron Jones*^b and Philip Mountford*^a

Author affiliations

* Corresponding authors

^a Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford, UK
E-mail: philip.mountford@chem.ox.ac.uk

^b School of Chemistry, Monash University, Melbourne, PO Box 23, Victoria, Australia
E-mail: Cameron.Jones@sci.monash.edu.au

^c Institut Charles Gerhardt Montpellier, UMR 5253 CNRS-UM2-ENSCM-UM1cc 1501, Place Eugène Bataillon, Montpellier Cedex 5, France
E-mail: clot@univ-montp2.fr

Abstract

The first structurally authenticated [2+2] cycloaddition products of any transition metal hydrazide complexes are reported; cycloaddition products of transition metal hydrazides with alkynes and heteroalkynes have been obtained for the first time; these are the first structurally authenticated cycloaddition products for any transition metal M [double bond, length as m-dash] NNR₂ functional group.

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Article information

DOI: https://doi.org/10.1039/B813911C
Article type: Communication
Submitted: 11 Aug 2008
Accepted: 04 Sep 2008
First published: 23 Sep 2008

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Chem. Commun., 2008, 5101-5103

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Cycloaddition reactions of transition metal hydrazides with alkynes and heteroalkynes: coupling of TiNNPh₂ with PhCCMe, PhCCH, MeCN and ^tBuCP

J. D. Selby, C. Schulten, A. D. Schwarz, A. Stasch, E. Clot, C. Jones and P. Mountford, Chem. Commun., 2008, 5101 DOI: 10.1039/B813911C

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