Issue 34, 2008
From the journal:

Chemical Communications

Gas-phase synthesis of the rare-gas carbene cation ArCH2+ using doubly ionised bromomethane as a superelectrophilic reagent

Daniela Ascenzi,a   Paolo Tosi,a   Jana Roithovábc  and  Detlef Schröder*c  

* Corresponding authors

a Department of Physics, University of Trento, Via Sommarive 14, Trento, Italy
E-mail: ascenzi@science.unitn.it
Fax: +39-0461-881696
Tel: +39-0461-881641

b Department of Organic Chemistry, Faculty of Sciences, Charles University in Prague, Hlavova 8, 12083 Prague 2, Czech Republic
E-mail: jana.roithova@natur.cuni.cz
Fax: +420 221 951 326
Tel: +420 221 951 322

c Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Flemingovo nám. 2, 16610 Prague 6, Czech Republic
E-mail: detlef.schroeder@uochb.cas.cz
Fax: +420 220 183 462
Tel: +420 220 183 463

Abstract

The bimolecular reaction of mass-selected CH3Br2+/CH2BrH2+ dications with argon leads to the rare-gas carbene cation ArCH2+, which represents an example of a new kind of organo rare-gas compound.

Graphical abstract: Gas-phase synthesis of the rare-gas carbene cation ArCH2+ using doubly ionised bromomethane as a superelectrophilic reagent

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Article information

DOI
https://doi.org/10.1039/B811115D
Article type
Communication
Submitted
30 Jun 2008
Accepted
11 Jul 2008
First published
29 Jul 2008

Chem. Commun., 2008, 4055-4057

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Gas-phase synthesis of the rare-gas carbene cation ArCH2+ using doubly ionised bromomethane as a superelectrophilic reagent

D. Ascenzi, P. Tosi, J. Roithová and D. Schröder, Chem. Commun., 2008, 4055 DOI: 10.1039/B811115D

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