Issue 37, 2008
From the journal:

Chemical Communications

Oxidative decarboxylative synthesis of 2-H-imidazolines from glyoxylic acid and 1,2-diamines†

Kenichi Murai,a   Maiko Morishita,a   Ryo Nakatani,a   Hiromichi Fujioka*a  and  Yasuyuki Kita*a  

* Corresponding authors

a Graduate School of Pharmaceutical Sciences, Osaka University, 1-6 Yamada-oka, Suita, Osaka 565-0871, Japan
E-mail: fujioka@phs.osaka-u.ac.jp, kita@phs.osaka-u.ac.jp
Fax: +81 6 6879 8229
Tel: +81 6 6879 8226

Abstract

A novel method to prepare 2-H-imidazolines from glyoxylic acid monohydrate and 1,2-diamines is described; the key reaction of this method is the oxidative decarboxylation of the 2-carboxy imidazolidines by NBS.

Graphical abstract: Oxidative decarboxylative synthesis of 2-H-imidazolines from glyoxylic acid and 1,2-diamines

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Article information

DOI
https://doi.org/10.1039/B807810F
Article type
Communication
Submitted
08 May 2008
Accepted
27 Jun 2008
First published
04 Aug 2008

Chem. Commun., 2008, 4498-4500

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Oxidative decarboxylative synthesis of 2-H-imidazolines from glyoxylic acid and 1,2-diamines

K. Murai, M. Morishita, R. Nakatani, H. Fujioka and Y. Kita, Chem. Commun., 2008, 4498 DOI: 10.1039/B807810F

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