Binary stacks of [CuC6F5]4 with arenes

Ami Doshi; Krishnan Venkatasubbaiah; Arnold L. Rheingold; Frieder Jäkle

doi:10.1039/B807128D

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Binary stacks of [CuC₆F₅]₄ with arenes†

Ami Doshi,^a Krishnan Venkatasubbaiah,^a Arnold L. Rheingold^b and Frieder Jäkle*^a

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* Corresponding authors

^a Department of Chemistry, Rutgers University-Newark, 73 Warren Street, Newark, USA
E-mail: fjaekle@rutgers.edu
Fax: +1 973 353 1264
Tel: +1 973 353 5064

^b Department of Chemistry and Biochemistry, University of California San Diego, 9500 Gilman Drive, La Jolla, USA

Abstract

Formation of the first binary stacks of an intact organocopper aggregate with the arenes naphthalene and 2,2′-bithiophene is reported; crystallographic data suggest that the supramolecular assembly process is supported by Cu–π, Cu–S, and perfluoroarene–arene π-interactions.

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Article information

DOI: https://doi.org/10.1039/B807128D
Article type: Communication
Submitted: 28 Apr 2008
Accepted: 06 Jun 2008
First published: 25 Jul 2008

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Chem. Commun., 2008, 4264-4266

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Binary stacks of [CuC₆F₅]₄ with arenes

A. Doshi, K. Venkatasubbaiah, A. L. Rheingold and F. Jäkle, Chem. Commun., 2008, 4264 DOI: 10.1039/B807128D

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Chemical Communications