Issue 8, 2007
From the journal:

New Journal of Chemistry

Design and preparation of neutral substituted fluorene- and carbazole-based platinum(ii)–acetylide complexes

Julie Batcha Seneclauze,a   Pascal Retailleaub  and  Raymond Ziessel*a  

* Corresponding authors

a Laboratoire de Chimie Moléculaire, École de Chimie, Polymères Matériaux (ECPM), Université Louis Pasteur (ULP), 25 rue Becquerel, France
E-mail: ziessel@chimie.u-strasbg.fr

b Laboratoire de Cristallochimie, ICSN-CNRS, Bât 27-1 avenue de la Terrasse, France

Abstract

Various combinations of mono- or diethynyl-substituted fluorene or carbazole building blocks were connected via a σ-bonded ethynyl linkage to ortho-metallated Pt(II) fragments, giving rise to phosphorescent mono- and dinuclear complexes for which the solubility and extent of delocalization could be tuned by the chemistry on the acidic methylene position of the fluorene.

Graphical abstract: Design and preparation of neutral substituted fluorene- and carbazole-based platinum(ii)–acetylide complexes

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Article information

DOI
https://doi.org/10.1039/B702374J
Article type
Letter
Submitted
14 Feb 2007
Accepted
23 Apr 2007
First published
01 Jun 2007

New J. Chem., 2007,31, 1412-1416

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Design and preparation of neutral substituted fluorene- and carbazole-based platinum(II)–acetylide complexes

J. B. Seneclauze, P. Retailleau and R. Ziessel, New J. Chem., 2007, 31, 1412 DOI: 10.1039/B702374J

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