Issue 2, 2007
From the journal:

New Journal of Chemistry

A novel trinuclear Re(i) complex containing 1,3,4-thiadiazole-2,5-dithiolate: structural and spectroscopic properties†

Biing-Chiau Tzeng,*a   Ya-Ling Wu,a   Gene-Hsiang Leeb  and  Shie-Ming Pengb  

* Corresponding authors

a Department of Chemistry and Biochemistry, National Chung Cheng University, 168 University Road, Min-Hsiung, Chia-Yi

b Department of Chemistry, National Taiwan University, 1, Sec. 4, Roosevelt Road, Taipei

Abstract

In the title complex [SSS(Re(CO)5)3](CF3SO3) (SSS = 1,3,4-thiadiazole-2,5-dithiolate), SSS adopts a two-S/one-N (κ3) coordination form, representing an unprecedented coordination pattern for this ligand. In addition, its solid-state structure confirms that an interesting anion π-interaction (2.880 Å) between the N-heterocyclic ligand and the CF3SO3− anion is observed.

Graphical abstract: A novel trinuclear Re(i) complex containing 1,3,4-thiadiazole-2,5-dithiolate: structural and spectroscopic properties

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Article information

DOI
https://doi.org/10.1039/B616122G
Article type
Letter
Submitted
06 Nov 2006
Accepted
14 Dec 2006
First published
10 Jan 2007

New J. Chem., 2007,31, 199-201

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A novel trinuclear Re(I) complex containing 1,3,4-thiadiazole-2,5-dithiolate: structural and spectroscopic properties

B. Tzeng, Y. Wu, G. Lee and S. Peng, New J. Chem., 2007, 31, 199 DOI: 10.1039/B616122G

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