Issue 11, 2007

Cyclometalationvs. Werner-type coordination of sterically enforced palladium(ii)-1,3-bis(pyridyl-2-imino)isoindolines (Pd-BPIs)

Abstract

The reaction of 1,3-bis(4,6-dimethylpyridyl-2-imino)isoindoline and palladium acetate in methanol selectively yields the expected acetato palladium N,N,N-chelate or a cyclometalated tetranuclear dimer depending on the stoichiometry of the reactants.

Graphical abstract: Cyclometalation vs. Werner-type coordination of sterically enforced palladium(ii)-1,3-bis(pyridyl-2-imino)isoindolines (Pd-BPIs)

Supplementary files

Article information

Article type
Communication
Submitted
10 Jan 2007
Accepted
01 Feb 2007
First published
14 Feb 2007

Dalton Trans., 2007, 1101-1103

Cyclometalation vs. Werner-type coordination of sterically enforced palladium(II)-1,3-bis(pyridyl-2-imino)isoindolines (Pd-BPIs)

M. Bröring and C. Kleeberg, Dalton Trans., 2007, 1101 DOI: 10.1039/B700400A

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