Issue 48, 2007
From the journal:

Chemical Communications

The N-donor stabilised cyclotriphosphazene hexacation [P3N3(DMAP)6]6+†

Ramamoorthy Boomishankar,a   Joanne Ledger,a   Jean-Baptiste Guilbaud,a   Neil L. Campbell,b   John Bacsa,a   Richard Bonar-Law,a   Yaroslav Z. Khimyaka  and  Alexander Steiner*a  

* Corresponding authors

a Department of Chemistry, University of Liverpool, Crown Street, Liverpool, UK
E-mail: a.steiner@liv.ac.uk

b Centre for Materials Discovery, Department of Chemistry, University of Liverpool, Crown Street, Liverpool, UK

Abstract

The cyclotriphosphazene P3N3Cl6 reacts with six equivalents of DMAP (4-(dimethylamino)pyridine) in superheated chloroform to form crystals of composition [P3N3(DMAP)6]Cl6·19CHCl3 comprising [P3N3(DMAP)6]6+ ions, which host five chloride ions in basket-type cavities on either side of the ring and at equatorial positions via tetradentate ortho-H-donor arrangements.

Graphical abstract: The N-donor stabilised cyclotriphosphazene hexacation [P3N3(DMAP)6]6+

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Article information

DOI
https://doi.org/10.1039/B713847D
Article type
Communication
Submitted
10 Sep 2007
Accepted
28 Sep 2007
First published
10 Oct 2007

Chem. Commun., 2007, 5152-5154

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The N-donor stabilised cyclotriphosphazene hexacation [P3N3(DMAP)6]6+

R. Boomishankar, J. Ledger, J. Guilbaud, N. L. Campbell, J. Bacsa, R. Bonar-Law, Y. Z. Khimyak and A. Steiner, Chem. Commun., 2007, 5152 DOI: 10.1039/B713847D

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