Issue 8, 2006

Tandem radical rearrangement/Pd-catalysed translocation of bicyclo[2.2.2]lactones. An efficient access to the oxa-triquinane core structure

Abstract

The skeletal rearrangement of bicyclo[2.2.2]lactones, involving a mild and chemoselective palladium-catalysed translocation key-step, provides an efficient and diastereoselective access to synthetically useful bicyclo[3.3.0]lactones.

Graphical abstract: Tandem radical rearrangement/Pd-catalysed translocation of bicyclo[2.2.2]lactones. An efficient access to the oxa-triquinane core structure

Supplementary files

Article information

Article type
Communication
Submitted
21 Dec 2005
Accepted
26 Feb 2006
First published
08 Mar 2006

Org. Biomol. Chem., 2006,4, 1464-1467

Tandem radical rearrangement/Pd-catalysed translocation of bicyclo[2.2.2]lactones. An efficient access to the oxa-triquinane core structure

J. Liao, N. Maulide, B. Augustyns and I. E. Markó, Org. Biomol. Chem., 2006, 4, 1464 DOI: 10.1039/B518121F

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