Issue 10, 2006
From the journal:

New Journal of Chemistry

Copper(i)-induced threading of two bis-macrocycles on two rods: a cyclic [4]rotaxane

Jean-Paul Collin,a   Julien Frey,a   Valérie Heitz,a   Efstathia Sakellariou,a   Jean-Pierre Sauvage*a  and  Christian Tocka  

* Corresponding authors

a Laboratoire de Chimie Organo-Minérale, LC3 UMR 7177 du CNRS, Institut Le Bel, Université Louis Pasteur, 4 rue Blaise Pascal, 67070 Strasbourg Cedex, France
E-mail: sauvage@chimie.u-strasbg.fr

Abstract

A cyclic pseudo-rotaxane tetramer has been synthesised quantitatively at room temperature by threading two two-coordination site rods through two bis-macrocycles in the presence of copper(I) as a template.

Graphical abstract: Copper(i)-induced threading of two bis-macrocycles on two rods: a cyclic [4]rotaxane

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Article information

DOI
https://doi.org/10.1039/B601703G
Article type
Letter
Submitted
06 Feb 2006
Accepted
13 Apr 2006
First published
17 May 2006

New J. Chem., 2006,30, 1386-1389

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Copper(I)-induced threading of two bis-macrocycles on two rods: a cyclic [4]rotaxane

J. Collin, J. Frey, V. Heitz, E. Sakellariou, J. Sauvage and C. Tock, New J. Chem., 2006, 30, 1386 DOI: 10.1039/B601703G

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