Issue 40, 2006
From the journal:

Dalton Transactions

Synthesis and structures of acyclic monoanionic tetradentate aza β-diketiminate complexes of magnesium, zinc, and cadmium†

Joseph M. Fritsch,ab   Kristen A. Thoresona  and  Kristopher McNeill*a  

* Corresponding authors

a Department of Chemistry, University of Minnesota, 207 Pleasant St SE, Minneapolis, MN, USA
E-mail: mcneill@chem.umn.edu
Fax: +1 612-626-7541
Tel: +1 612-625-0781

b Natural Science Division, Pepperdine University, 24255 Pacific Coast Highway, Malibu, CA, USA
E-mail: joseph.fritsch@pepperdine.edu
Fax: +1-310-506-4785
Tel: +1–310–506–6705

Abstract

An acyclic monoanionic tetradentate nitrogen ligand was prepared through the condensation of 2-(4-tolyl)-malondialdehyde and 8-aminoquinoline to give (BDIQQ)H where (BDIQQ)H = (8-quinolyl)-NCHC(4-tolyl)CHNH-(8-quinolyl). Metal complexes, (BDIQQ)MX, were prepared where MX = MgBr 2, ZnCl 3, and CdOAc 4. The spectroscopic and crystallographic properties of compounds 2, 3, and 4 were explored. Structures of complexes 2, 3, 4, and the tridentate ligand, (BDIQ)OH, 5, are reported.

Graphical abstract: Synthesis and structures of acyclic monoanionic tetradentate aza β-diketiminate complexes of magnesium, zinc, and cadmium

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Article information

DOI
https://doi.org/10.1039/B609616F
Article type
Paper
Submitted
06 Jul 2006
Accepted
14 Aug 2006
First published
30 Aug 2006

Dalton Trans., 2006, 4814-4820

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Synthesis and structures of acyclic monoanionic tetradentate aza β-diketiminate complexes of magnesium, zinc, and cadmium

J. M. Fritsch, K. A. Thoreson and K. McNeill, Dalton Trans., 2006, 4814 DOI: 10.1039/B609616F

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