Issue 31, 2006
From the journal:

Chemical Communications

Eu(iii) dithiocarbamate complex and N-p-tolylsulfonylphenylalanine as a novel chiral catalyst for the asymmetric synthesis of cyanohydrins†

Juliana A. Vale,*a   Wagner M. Faustino,a   Paulo H. Menezesa  and  Gilberto F. de Sáa  

* Corresponding authors

a Departamento de Química Fundamental, Universidade Federal de Pernambuco, Recife/PE, Brasil
E-mail: julianadqf@yahoo.com.br
Fax: +55-81-21268441
Tel: +55-81-2126-8440

Abstract

The use of a new chiral lanthanide complex derived from a europium dithiocarbamate complex and a N-tosylated amino acid for the asymmetric synthesis of cyanohydrins is described. In some cases, high enantioselectivities were observed.

Graphical abstract: Eu(iii) dithiocarbamate complex and N-p-tolylsulfonylphenylalanine as a novel chiral catalyst for the asymmetric synthesis of cyanohydrins

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Article information

DOI
https://doi.org/10.1039/B607741M
Article type
Communication
Submitted
31 May 2006
Accepted
13 Jun 2006
First published
30 Jun 2006

Chem. Commun., 2006, 3340-3342

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Eu(III) dithiocarbamate complex and N-p-tolylsulfonylphenylalanine as a novel chiral catalyst for the asymmetric synthesis of cyanohydrins

J. A. Vale, W. M. Faustino, P. H. Menezes and G. F. de Sá, Chem. Commun., 2006, 3340 DOI: 10.1039/B607741M

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