Issue 31, 2006
From the journal:

Chemical Communications

Novel aziridination of olefins: direct synthesis from sulfonamides using t-BuOI†

Satoshi Minakata,*a   Yoshinobu Morino,a   Yoji Oderaotoshia  and  Mitsuo Komatsu*a  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka, Japan
E-mail: minakata@chem.eng.osaka-u.ac.jp
Fax: +81-6-6879-7402

Abstract

tert-Butyl hypoiodite (t-BuOI) was found to be a powerful reagent for synthesis of aziridines from olefins and sulfonamides. The aziridination of olefins was achieved by using sulfonamides with t-BuOI. Our preliminary findings represent the example of metal-free aziridination of olefins with readily accessible sulfonamides as a nitrogen source.

Graphical abstract: Novel aziridination of olefins: direct synthesis from sulfonamides using t-BuOI

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Article information

DOI
https://doi.org/10.1039/B606499J
Article type
Communication
Submitted
09 May 2006
Accepted
12 Jun 2006
First published
30 Jun 2006

Chem. Commun., 2006, 3337-3339

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Novel aziridination of olefins: direct synthesis from sulfonamides using t-BuOI

S. Minakata, Y. Morino, Y. Oderaotoshi and M. Komatsu, Chem. Commun., 2006, 3337 DOI: 10.1039/B606499J

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