Issue 23, 2006
From the journal:

Chemical Communications

A normal equilibrium isotope effect for oxidative addition of H2 to (η6-anthracene)Mo(PMe3)3†

Guang Zhu,a   Kevin E. Janaka  and  Gerard Parkin*a  

* Corresponding authors

a Department of Chemistry, Columbia University, New York, USA
E-mail: parkin@columbia.edu

Abstract

Oxidative addition of H2 and D2 to the anthracene complex (η6-AnH)Mo(PMe3)3 giving (η4-AnH)Mo(PMe3)3X2 (X = H, D) is characterized by a normal equilibrium isotope effect (KH/KD > 1) at temperatures close to ambient; calculations on (η4-AnH)Mo(PH3)3H2 indicate that this is a consequence of relatively low energy Mo–H vibrational modes.

Graphical abstract: A normal equilibrium isotope effect for oxidative addition of H2 to (η6-anthracene)Mo(PMe3)3

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Article information

DOI
https://doi.org/10.1039/B604159K
Article type
Communication
Submitted
20 Mar 2006
Accepted
10 Apr 2006
First published
05 May 2006

Chem. Commun., 2006, 2501-2503

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A normal equilibrium isotope effect for oxidative addition of H2 to (η6-anthracene)Mo(PMe3)3

G. Zhu, K. E. Janak and G. Parkin, Chem. Commun., 2006, 2501 DOI: 10.1039/B604159K

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