Issue 3, 2006
From the journal:

Chemical Communications

Supramolecular shuttle and protective agent: a multiple role of methylated cyclodextrins in the chemoselective hydrogenation of benzene derivatives with ruthenium nanoparticles†

Audrey Nowicki,a   Yong Zhang,a   Bastien Léger,a   Jean-Paul Rolland,b   Hervé Bricout,c   Eric Monflierc  and  Alain Roucoux*a  

* Corresponding authors

a UMR CNRS 6052 “Synthèses et Activations de Biomolécules”, Ecole Nationale Supérieure de Chimie de Rennes, Institut de Chimie de Rennes, Avenue du Général Leclerc, Rennes, France
E-mail: Alain.Roucoux@ensc-rennes.fr
Fax: +33 (0)223 238 199

b UMR CNRS 6026 “Interactions Cellulaires et Moléculaires”, Université de Rennes I, Rennes, France

c Laboratoire de Physico-chimie des Interfaces et Applications-FRE CNRS 2485, Faculté Jean Perrin, Université d'Artois, Lens Cedex, France

Abstract

Efficient chemoselectivities have been obtained in the hydrogenation of benzene derivatives under biphasic liquid–liquid conditions using Ru(0) nanoparticles stabilized and controlled by the relevant choice of cavity and methylation degree of cyclodextrins.

Graphical abstract: Supramolecular shuttle and protective agent: a multiple role of methylated cyclodextrins in the chemoselective hydrogenation of benzene derivatives with ruthenium nanoparticles

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Article information

DOI
https://doi.org/10.1039/B512838B
Article type
Communication
Submitted
13 Sep 2005
Accepted
18 Oct 2005
First published
22 Nov 2005

Chem. Commun., 2006, 296-298

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Supramolecular shuttle and protective agent: a multiple role of methylated cyclodextrins in the chemoselective hydrogenation of benzene derivatives with ruthenium nanoparticles

A. Nowicki, Y. Zhang, B. Léger, J. Rolland, H. Bricout, E. Monflier and A. Roucoux, Chem. Commun., 2006, 296 DOI: 10.1039/B512838B

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