Issue 3, 2006
From the journal:

Chemical Communications

Readily available, recoverable and soluble polymer-monophosphite ligands for highly enantioselective Rh-catalyzed hydrogenation†

Xiang-Ping Hu,a   Jia-Di Huang,ab   Qing-Heng Zengab  and  Zhuo Zheng*a  

* Corresponding authors

a Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China
E-mail: zhengz@dicp.ac.cn
Fax: (+86) 411-84684746
Tel: (+86) 411-84669077

b Graduate School of Chinese Academy of Sciences, Beijing, China

Abstract

A new family of readily available, recoverable and soluble polymer-monophosphite ligands were prepared and successfully used in the Rh-catalyzed asymmetric hydrogenation of enamides and β-dehydroamino acid esters, in which up to 99 and 99.9% ee were obtained, respectively.

Graphical abstract: Readily available, recoverable and soluble polymer-monophosphite ligands for highly enantioselective Rh-catalyzed hydrogenation

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Article information

DOI
https://doi.org/10.1039/B511323G
Article type
Communication
Submitted
09 Aug 2005
Accepted
31 Oct 2005
First published
25 Nov 2005

Chem. Commun., 2006, 293-295

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Readily available, recoverable and soluble polymer-monophosphite ligands for highly enantioselective Rh-catalyzed hydrogenation

X. Hu, J. Huang, Q. Zeng and Z. Zheng, Chem. Commun., 2006, 293 DOI: 10.1039/B511323G

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