Issue 5, 2005
From the journal:

Organic & Biomolecular Chemistry

A highly stereoselective ether directed palladium catalysed aza-Claisen rearrangement†

Andrew G. Jamiesona  and  Andrew Sutherland*a  

* Corresponding authors

a Department of Chemistry, The Joseph Black Building, University of Glasgow, Glasgow, UK
E-mail: andrews@chem.gla.ac.uk
Fax: 0141 330 4888
Tel: 0141 330 5936

Abstract

A highly stereoselective rearrangement of allylic trichloroacetimidates to allylic trichloroamides has been achieved using adjacent ether groups to direct facial coordination of the palladium(II) catalyst.

Graphical abstract: A highly stereoselective ether directed palladium catalysed aza-Claisen rearrangement

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Article information

DOI
https://doi.org/10.1039/B501346C
Article type
Communication
Submitted
06 Oct 2004
Accepted
26 Jan 2005
First published
07 Feb 2005

Org. Biomol. Chem., 2005,3, 735-736

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A highly stereoselective ether directed palladium catalysed aza-Claisen rearrangement

A. G. Jamieson and A. Sutherland, Org. Biomol. Chem., 2005, 3, 735 DOI: 10.1039/B501346C

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