Issue 5, 2005
From the journal:

Organic & Biomolecular Chemistry

Synthesis of the β-hydroxydopa–γ-hydroxy-δ-sulfinylnorvaline component of ustiloxins A and B

Luke Hunter,a   Malcolm D. McLeoda  and  Craig A. Hutton*ab  

* Corresponding authors

a School of Chemistry, University of Sydney, NSW, Australia

b School of Chemistry, University of Melbourne, VIC, Australia
E-mail: chutton@unimelb.edu.au
Fax: +61 3 9347 5180
Tel: +61 3 8344 6482

Abstract

The dopa–sulfinylnorvaline component of ustiloxins A and B has been prepared using an Evans salen–Al-catalysed aldol reaction with a 6-mercaptoisovanillin derivative, followed by incorporation of the norvaline group and asymmetric oxidation of the resulting sulfide to give the corresponding sulfoxide.

Graphical abstract: Synthesis of the β-hydroxydopa–γ-hydroxy-δ-sulfinylnorvaline component of ustiloxins A and B

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Article information

DOI
https://doi.org/10.1039/B418876D
Article type
Communication
Submitted
17 Dec 2004
Accepted
13 Jan 2005
First published
03 Feb 2005

Org. Biomol. Chem., 2005,3, 732-734

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Synthesis of the β-hydroxydopa–γ-hydroxy-δ-sulfinylnorvaline component of ustiloxins A and B

L. Hunter, M. D. McLeod and C. A. Hutton, Org. Biomol. Chem., 2005, 3, 732 DOI: 10.1039/B418876D

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