Hydrogenation versus hydrogenolysis with a safe, selective and reusable catalyst: palladium black on Teflon®

Damien Belotti; Guillaume Cantagrel; Catherine Combellas; Janine Cossy; Frédéric Kanoufi; Sandra Nunige

doi:10.1039/B501096A

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Hydrogenationversus hydrogenolysis with a safe, selective and reusable catalyst: palladium black on Teflon^®

Damien Belotti,^a Guillaume Cantagrel,^ab Catherine Combellas,^b Janine Cossy,*^a Frédéric Kanoufi^b and Sandra Nunige^b

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* Corresponding authors

^a Laboratoire de Chimie Organique associé au CNRS, ESPCI, 10 rue Vauquelin, 75231 Paris Cedex 05 - France
E-mail: janine.cossy@espci.fr
Fax: +33 1 40 79 46 60
Tel: +33 1 40 79 44 29

^b Laboratoire Environnement et Chimie Analytique associé au CNRS, ESPCI, 10 rue Vauquelin, 75231 Paris Cedex 05 - France

Abstract

Palladium black deposit is obtained by reduction and metallization of the Teflon^® polymer surface of magnetic stirring bars. These stirring bars can be used to perform selective hydrogenation of olefins and acetylenic compounds whilst hydrogenolysis is not observed.

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Article information

DOI: https://doi.org/10.1039/B501096A
Article type: Letter
Submitted: 21 Jan 2005
Accepted: 18 Mar 2005
First published: 27 Apr 2005

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New J. Chem., 2005,29, 761-764

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Hydrogenation versus hydrogenolysis with a safe, selective and reusable catalyst: palladium black on Teflon^®

D. Belotti, G. Cantagrel, C. Combellas, J. Cossy, F. Kanoufi and S. Nunige, New J. Chem., 2005, 29, 761 DOI: 10.1039/B501096A

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