Issue 44, 2005
From the journal:

Chemical Communications

An octanuclear [Co(ii)2–Co(iii)2]2 interlocked grid—example of an inorganic [2]catenane†

Tareque S. M. Abedin,a   Laurence K. Thompson*a  and  David O. Millera  

* Corresponding authors

a Department of Chemistry, Memorial University, St. John's, NL, Canada

Abstract

An oxalic dihydrazide based flexible polydentate amidrazone ligand undergoes spontaneous [2 × 2] grid assembly, followed by partial disassembly, and then reassembly in the presence of Co(NO3)2·6H2O and NH4(NCS) to form a unique octanuclear [Co(II)2–Co(III)2]2 interlocked, single braided 4 + 4 [2]catenane.

Graphical abstract: An octanuclear [Co(ii)2–Co(iii)2]2 interlocked grid—example of an inorganic [2]catenane

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Article information

DOI
https://doi.org/10.1039/B510755E
Article type
Communication
Submitted
28 Jul 2005
Accepted
13 Sep 2005
First published
05 Oct 2005

Chem. Commun., 2005, 5512-5514

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An octanuclear [Co(II)2–Co(III)2]2 interlocked grid—example of an inorganic [2]catenane

T. S. M. Abedin, L. K. Thompson and D. O. Miller, Chem. Commun., 2005, 5512 DOI: 10.1039/B510755E

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