Issue 44, 2005
From the journal:

Chemical Communications

Microporous chiral metal coordination polymers: hydrothermal synthesis, channel engineering and stability of lanthanide tartrates†

Samadara Thushari,a   John A. K. Cha,a   Herman H.-Y. Sung,a   Stephen S.-Y. Chui,a   Andy L.-F. Leung,a   Yu-Fong Yena  and  Ian D. Williams*a  

* Corresponding authors

a Department of Chemistry, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China
E-mail: chwill@ust.hk
Fax: +(852) 3106-3446
Tel: +(852) 2358-7384

Abstract

L-Tartrate ions can endure hydrothermal conditions up to 160 °C to form the robust, enantiopure open-framework coordination polymers [Ln2(L-TAR)3(H2O)2]3H2O, 1; the addition of succinate results in formation of the related [Ln2(L-TAR)2(SUC)(H2O)2]5.5H2O, 2 with larger channels than 1, whereas racemic D/L-tartrate gives the more condensed [Ln2(D/L-TAR)3(H2O)2], 3. TAR = [C4H4O6]2−.

Graphical abstract: Microporous chiral metal coordination polymers: hydrothermal synthesis, channel engineering and stability of lanthanide tartrates

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Article information

DOI
https://doi.org/10.1039/B508574H
Article type
Communication
Submitted
17 Jun 2005
Accepted
03 Aug 2005
First published
12 Oct 2005

Chem. Commun., 2005, 5515-5517

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Microporous chiral metal coordination polymers: hydrothermal synthesis, channel engineering and stability of lanthanide tartrates

S. Thushari, J. A. K. Cha, H. H.-Y. Sung, S. S.-Y. Chui, A. L.-F. Leung, Y. Yen and I. D. Williams, Chem. Commun., 2005, 5515 DOI: 10.1039/B508574H

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