Issue 16, 2005
From the journal:

Chemical Communications

Unprecedented reversible coupling of alkynyl and phosphide ligands on a dinuclear platinum framework†

Alberto Albinati,a   Valeria Filippi,b   Piero Leoni,*b   Lorella Marchetti,b   Marco Pasqualib  and  Vincenzo Passarellib  

* Corresponding authors

a Dipartimento di Chimica Strutturale e Stereochimica Inorganica (DCSSI) e Facoltà di Farmacia, Università di Milano, Via Venezian 21, I-20133 Milano, Italy

b Dipartimento di Chimica e Chimica Industriale, Università di Pisa, Via Risorgimento 35, I–56126 Pisa, Italy
E-mail: leoni@dcci.unipi.it
Fax: +39 050 2219246
Tel: +39 050 2219217

Abstract

The reductive coupling of the bridging phosphide and the adjacent σ-alkynyl moieties in [Pt2(μ-PtBu2){μ,η1:η2-C(Ph)CH2}(C[triple bond, length as m-dash]C–Ph)(CO)(PtBu2H)(Br)] is promoted by bromide abstraction and is reversed by adding NnBu4Br.

Graphical abstract: Unprecedented reversible coupling of alkynyl and phosphide ligands on a dinuclear platinum framework

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Article information

DOI
https://doi.org/10.1039/B418893D
Article type
Communication
Submitted
16 Dec 2004
Accepted
18 Feb 2005
First published
07 Mar 2005

Chem. Commun., 2005, 2155-2157

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Unprecedented reversible coupling of alkynyl and phosphide ligands on a dinuclear platinum framework

A. Albinati, V. Filippi, P. Leoni, L. Marchetti, M. Pasquali and V. Passarelli, Chem. Commun., 2005, 2155 DOI: 10.1039/B418893D

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