Issue 16, 2005
From the journal:

Chemical Communications

Isolation of a new two-dimensional honeycomb carbonato-bridged copper(ii) complex exhibiting long-range ferromagnetic ordering†

Arpi Majumder,a   Chirantan Roy Choudhury,a   Samiran Mitra,*a   Georgina M. Rosair,b   M. Salah El Fallah*c  and  Joan Ribasc  

* Corresponding authors

a Department of Chemistry, Jadavpur University, Kolkata-700 032, India
E-mail: smitra_2002@yahoo.com

b Department of Chemistry, Heriot-Watt University, Edinburgh, UK

c Department de Quimica Inorganica, Universitat de Barcelona, Marti I Franques, 1-11, 08028-Barcelona, Spain
E-mail: salah.elfallah@qi.ub.es

Abstract

Atmospheric CO2 fixation by an aqueous solution containing Cu(ClO4)2·6H2O and 4-aminopyridine (4-apy) yields a novel example of a two-dimensional μ3-CO3 bridged copper(II) complex {[Cu(4-apy)2]3(μ3-CO3)2(ClO4)2·½CH3OH}n1 that has been characterized by IR, UV and X-ray crystallography; preliminary magnetic measurements show that complex 1 exhibits long-range ordered ferromagnetic coupling.

Graphical abstract: Isolation of a new two-dimensional honeycomb carbonato-bridged copper(ii) complex exhibiting long-range ferromagnetic ordering

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Article information

DOI
https://doi.org/10.1039/B417019A
Article type
Communication
Submitted
09 Nov 2004
Accepted
21 Feb 2005
First published
07 Mar 2005

Chem. Commun., 2005, 2158-2160

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Isolation of a new two-dimensional honeycomb carbonato-bridged copper(II) complex exhibiting long-range ferromagnetic ordering

A. Majumder, C. R. Choudhury, S. Mitra, G. M. Rosair, M. S. El Fallah and J. Ribas, Chem. Commun., 2005, 2158 DOI: 10.1039/B417019A

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