Issue 10, 2004
From the journal:

Green Chemistry

Nickel-catalyzed dehydrative transformation of CO2 to urethanes

Mahmut Abla,a   Jun-Chul Choia  and  Toshiyasu Sakakura*a  

* Corresponding authors

a National Institute of Advanced Industrial Science and Technology (AIST), Higashi, AIST Central 5, Tsukuba, Ibaraki 305-8565, Japan
E-mail: t-sakakura@aist.go.jp
Fax: +81-298-61-4719
Tel: +81-298-61-4719

Abstract

Ni(OAc)2-bipyridine or phenanthroline complexes catalyze the environmentally benign synthesis of urethane from amine, alcohol, and CO2 without toxic and corrosive phosgene; electron-donating and rigid ligands on Ni promote the reaction.

Graphical abstract: Nickel-catalyzed dehydrative transformation of CO2 to urethanes

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Article information

DOI
https://doi.org/10.1039/B408429B
Article type
Paper
Submitted
03 Jun 2004
Accepted
14 Jul 2004
First published
24 Sep 2004

Green Chem., 2004,6, 524-525

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Nickel-catalyzed dehydrative transformation of CO2 to urethanes

M. Abla, J. Choi and T. Sakakura, Green Chem., 2004, 6, 524 DOI: 10.1039/B408429B

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