Issue 20, 2004
From the journal:

Chemical Communications

Oligomer preparation from hexane by radical polyaddition with bis(α-trifluoromethyl-β,β-difluorovinyl) terephthalate†

Tadashi Narita,*a   Hiroshi Hamanab  and  Satoshi Hattoria  

* Corresponding authors

a Department of Material Science and Engineering, Graduate School of Engineering, Saitma Institute of Technology, 1690 Fusaiji, Okabe, Japan
E-mail: narita@sit.ac.jp

b Department of Applied Chemistry, Faculty of Engineering, Saitama Institute of Technology, 1690 Fusaiji, Okabe, Japan

Abstract

Polymer preparation from hexane as a starting material by radical polyaddition with bis(α-trifluoromethyl-β,β-difluorovinyl) terephthalate [CF2[double bond, length as m-dash]C(CF3)OCOC6H4COO–C(CF3)[double bond, length as m-dash]CF2] was investigated to afford polymers bearing a molecular weight of as high as 5.5 × 103, and the polyaddition mechanism including 1,5-radical shift mechanism was proposed.

Graphical abstract: Oligomer preparation from hexane by radical polyaddition with bis(α-trifluoromethyl-β,β-difluorovinyl) terephthalate

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Article information

DOI
https://doi.org/10.1039/B406116K
Article type
Communication
Submitted
22 Apr 2004
Accepted
21 Jul 2004
First published
07 Sep 2004

Chem. Commun., 2004, 2340-2341

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Oligomer preparation from hexane by radical polyaddition with bis(α-trifluoromethyl-β,β-difluorovinyl) terephthalate

T. Narita, H. Hamana and S. Hattori, Chem. Commun., 2004, 2340 DOI: 10.1039/B406116K

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