Issue 9, 2004
From the journal:

Chemical Communications

Desymmetrization of meso-dienyne by asymmetric Pauson–Khand type reaction catalysts†

Nakcheol Jeong,*a   Dong Hoon Kima  and  Jun Hun Choia  

* Corresponding authors

a Department of Chemistry, Division of Molecular Engineering and Chemistry, Korea University, Seoul, 136-701, Korea

Abstract

Desymmetrization of the meso dienynes, such as propargyl 1-vinylallyl N-tosylamides (1a–c) and propargyl 1-vinylallyl ethers (1d–e), by asymmetric Pauson–Khand type reaction catalysts was studied. The corresponding vinyl substituted bicyclic pentenones (2 and 3) were obtained with high diastereoselectivity and enantioselectivity.

Graphical abstract: Desymmetrization of meso-dienyne by asymmetric Pauson–Khand type reaction catalysts

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Article information

DOI
https://doi.org/10.1039/B401288G
Article type
Communication
Submitted
27 Jan 2004
Accepted
11 Mar 2004
First published
08 Apr 2004

Chem. Commun., 2004, 1134-1135

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Desymmetrization of meso-dienyne by asymmetric Pauson–Khand type reaction catalysts

N. Jeong, D. H. Kim and J. H. Choi, Chem. Commun., 2004, 1134 DOI: 10.1039/B401288G

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