Issue 6, 2004
From the journal:

Chemical Communications

Highly diastereoselective synthesis of anti-γ-N-benzylamino-β-hydroxyphosphonates

Mario Ordóñez,*a   Ricardo de la Cruz-Cordero,a   Citlali Quiñónesa  and  Angelina González-Moralesa  

* Corresponding authors

a Centro de Investigaciones Químicas, Universidad Autónoma del Estado de Morelos, Av. Universidad 1001, 62210 Cuernavaca, Mor., Mexico
E-mail: palacios@buzon.uaem.mx
Fax: 52(777)3297997
Tel: 52(777)3297997

Abstract

The reduction of γ-N-benzylamino-β-ketophosphonates 7 derived from readily available amino acids can be carried out stereoselectively with Zn(BH4)2 at −78 °C to produce the anti-γ-amino-β-hydroxyphosphonates 8.

Graphical abstract: Highly diastereoselective synthesis of anti-γ-N-benzylamino-β-hydroxyphosphonates

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Article information

DOI
https://doi.org/10.1039/B316262A
Article type
Communication
Submitted
12 Dec 2003
Accepted
14 Jan 2004
First published
10 Feb 2004

Chem. Commun., 2004, 672-673

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Highly diastereoselective synthesis of anti-γ-N-benzylamino-β-hydroxyphosphonates

M. Ordóñez, R. de la Cruz-Cordero, C. Quiñónes and A. González-Morales, Chem. Commun., 2004, 672 DOI: 10.1039/B316262A

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