Issue 6, 2004
From the journal:

Chemical Communications

Superoxide-stable ionic liquids: new and efficient media for electrosynthesis of functional siloxanes

Bruno Martiz,a   Robert Keyrouz,b   Said Gmouh,b   Michel Vaultierb  and  Viatcheslav Jouikov*b  

* Corresponding authors

a Departamento de Química Orgánica, Facultad de Quimica, Universidad de Murcia, 30100 Murcia, Spain
E-mail: bmliza@um.es
Fax: 34 968 364148
Tel: 34 968 367593

b Laboratory of Molecular and Macromolecular Electrochemistry, UMR 6510, University of Rennes I, 35042 Rennes, France
E-mail: vjouikov@univ-rennes1.fr
Fax: 33 2323 6292
Tel: 33 2323 6292

Abstract

The electrogeneration of diorganylsilanones from difunctional precursors Y(CH2)3(Me)SiX2 and Ph2SiX2 (Y = NH2, CF3, CN; X = Cl, OEt, OMe), performed in the presence of hexamethyldisiloxane or hexamethylcyclotrisiloxane (D3) in the ionic liquids [C5H5NC8F18]·NTf2, [C5H5NC18H38]·NTf2 and Me3BuN·NTf2, which reveal high solubility of oxygen and are inert toward superoxide anion, allows functionalized siloxanes to be produced selectively in good isolated yields.

Graphical abstract: Superoxide-stable ionic liquids: new and efficient media for electrosynthesis of functional siloxanes

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/B313832A
Article type
Communication
Submitted
31 Oct 2003
Accepted
23 Jan 2004
First published
10 Feb 2004

Chem. Commun., 2004, 674-675

Permissions

Request permissions

Superoxide-stable ionic liquids: new and efficient media for electrosynthesis of functional siloxanes

B. Martiz, R. Keyrouz, S. Gmouh, M. Vaultier and V. Jouikov, Chem. Commun., 2004, 674 DOI: 10.1039/B313832A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements