Issue 4, 2004
From the journal:

Chemical Communications

A new type of entanglement involving one-dimensional ribbons of rings catenated to a three-dimensional network in the nanoporous structure of [Co(bix)2(H2O)2](SO4)·7H2O [bix = 1,4-bis(imidazol-1-ylmethyl)benzene]†

Lucia Carlucci,a   Gianfranco Ciani*a  and  Davide M. Proserpioa  

* Corresponding authors

a Dipartimento di Chimica Strutturale e Stereochimica Inorganica, Via G. Venezian 21, 20133 Milano, Italy
E-mail: davide.proserpio@istm.cnr.it

Abstract

CoII sulfate reacts with the flexible ligand 1,4-bis(imidazol-1-ylmethyl)benzene (bix) to yield the coordination network [Co(bix)2(H2O)2](SO4)·7H2O, containing polymeric ribbons of rings which penetrate and catenate a 3D single frame of the CdSO4 topology, to produce an open-channel entangled architecture with nanoporous behaviour.

Graphical abstract: A new type of entanglement involving one-dimensional ribbons of rings catenated to a three-dimensional network in the nanoporous structure of [Co(bix)2(H2O)2](SO4)·7H2O [bix = 1,4-bis(imidazol-1-ylmethyl)benzene]

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Article information

DOI
https://doi.org/10.1039/B314322H
Article type
Communication
Submitted
11 Nov 2003
Accepted
16 Dec 2003
First published
20 Jan 2004

Chem. Commun., 2004, 380-381

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A new type of entanglement involving one-dimensional ribbons of rings catenated to a three-dimensional network in the nanoporous structure of [Co(bix)2(H2O)2](SO4)·7H2O [bix = 1,4-bis(imidazol-1-ylmethyl)benzene]

L. Carlucci, G. Ciani and D. M. Proserpio, Chem. Commun., 2004, 380 DOI: 10.1039/B314322H

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