Issue 1, 2004
From the journal:

Chemical Communications

A general entry to linear, dendritic and branched thiourea-linked glycooligomers as new motifs for phosphate ester recognition in water†

José L. Jiménez Blanco,a   Purificación Bootello,a   Carmen Ortiz Mellet,*a   Ricardo Gutiérrez Gallegob  and  José M. García Fernández*c  

* Corresponding authors

a Departamento de Química Orgánica, Facultad de Química, Universidad de Sevilla, Apartado 553, E-41071 Sevilla, Spain
E-mail: mellet@us.es
Fax: +34 954624960
Tel: +34 954557150

b Pharmacology Research Unit, Municipal Institute of Medicinal Research (IMIM), Department of Experimental and Health Sciences, University Pompeu Fabra, Doctor Aiguader 80, E-08003 Barcelona, Spain

c Instituto de Investigaciones Químicas, CSIC, Américo Vespucio s/n, Isla de la Cartuja, E-41092 Sevilla, Spain
E-mail: jogarcia@cica.es
Fax: +34 954460565
Tel: +34 954489559

Abstract

A blockwise iterative synthetic strategy for the preparation of linear, dendritic and branched full-carbohydrate architectures has been developed by using sugar azido(carbamate) isothiocyanates as key templates; the presence of intersaccharide thiourea bridges provides anchoring points for hydrogen bond-directed molecular recognition of phosphate esters in water.

Graphical abstract: A general entry to linear, dendritic and branched thiourea-linked glycooligomers as new motifs for phosphate ester recognition in water

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Article information

DOI
https://doi.org/10.1039/B312743P
Article type
Communication
Submitted
13 Oct 2003
Accepted
11 Nov 2003
First published
18 Nov 2003

Chem. Commun., 2004, 92-93

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A general entry to linear, dendritic and branched thiourea-linked glycooligomers as new motifs for phosphate ester recognition in water

J. L. Jiménez Blanco, P. Bootello, C. Ortiz Mellet, R. Gutiérrez Gallego and J. M. García Fernández, Chem. Commun., 2004, 92 DOI: 10.1039/B312743P

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