Issue 1, 2004
From the journal:

Chemical Communications

Switching extended 1,3-diequatorial and bent 1,3-diaxial states of a disubstituted hinge sugar by ligand exchange reactions on Pt(ii)†

Takuhiro Izumi,a   Hironobu Hashimotoa  and  Hideya Yuasa*a  

* Corresponding authors

a Department of Life Science, Graduate School of Bioscience and Biotechnology, Tokyo Institute of Technology, 4259 Nagatsutacho, Midoriku, Yokohama 2268501, Japan
E-mail: hyuasa@bio.titech.ac.jp

Abstract

The bent conformation of a trisaccharide containing 2,4-diaminoxylopyranoside, in which both end sugars are presented in 1,3-diaxial orientation, is fixed by chelation of the diamino groups to Pt(II) and unfixed by a ligand exchange reaction with NaCN or thiourea giving its extended conformation.

Graphical abstract: Switching extended 1,3-diequatorial and bent 1,3-diaxial states of a disubstituted hinge sugar by ligand exchange reactions on Pt(ii)

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B311811H
Article type
Communication
Submitted
26 Sep 2003
Accepted
30 Oct 2003
First published
20 Nov 2003

Chem. Commun., 2004, 94-95

Permissions

Request permissions

Switching extended 1,3-diequatorial and bent 1,3-diaxial states of a disubstituted hinge sugar by ligand exchange reactions on Pt(II)

T. Izumi, H. Hashimoto and H. Yuasa, Chem. Commun., 2004, 94 DOI: 10.1039/B311811H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements