Issue 8, 2003
From the journal:

Organic & Biomolecular Chemistry

Labeling of organic biomolecules with ethynylferrocene

Evdoxia Coutouli-Argyropoulou,*a   Maria Tsitabani,a   Georgios Petrantonakis,a   Aris Terzisb  and  Catherine Raptopouloub  

* Corresponding authors

a Department of Chemistry, Aristotle University of Thessaloniki, 541 24 Thessaloniki, Greece
E-mail: evd@chem.auth.gr
Fax: ++310997679
Tel: ++310997733

b Institute of Materials Science, NCSR “Demokritos”, 15310 Aghia Paraskevi, Attiki, Greece
E-mail: aterzis@ims.demokritos.gr
Fax: ++0106519430
Tel: ++0106503346

Abstract

The Sonogashira coupling reaction of ethynylferrocene with adenine, uracil, tyrosine and steroid derivatives was studied; with the exception of tyrosine it was proved to be a good route for the attachment of ferrocene to these representative biomolecules. In addition the transformation of alkynyl uracil to furanopyrimidone derivatives was investigated and the formation of the furanopyrimidone ring was confirmed by an X-ray crystallographic analysis carried out on product 16.

Graphical abstract: Labeling of organic biomolecules with ethynylferrocene

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Article information

DOI
https://doi.org/10.1039/B300191A
Article type
Paper
Submitted
07 Jan 2003
Accepted
04 Mar 2003
First published
26 Mar 2003

Org. Biomol. Chem., 2003,1, 1382-1388

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Labeling of organic biomolecules with ethynylferrocene

E. Coutouli-Argyropoulou, M. Tsitabani, G. Petrantonakis, A. Terzis and C. Raptopoulou, Org. Biomol. Chem., 2003, 1, 1382 DOI: 10.1039/B300191A

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