Issue 8, 2003
From the journal:

Organic & Biomolecular Chemistry

Syntheses of the stereoisomers of neolignans morinol C and D

Satoshi Yamauchi*a  and  Hidemitsu Unob  

* Corresponding authors

a Department of Agriculture, Ehime University, Tarumi 3-5-7, Matsuyama, Ehime,790-8566, Japan
E-mail: syamauch@agr.ehime-u.ac.jp
Fax: +81-89-977-4364

b Advanced Instrumentation Center for Chemical Analysis, Ehime University, Bunkyo-cho 2-5, Matsuyama 790-8577, Japan

Abstract

Morinol C and morinol D are neolignans isolated from the Chinese medicinal herb Morina chinensis as racemates. (1R,2R)-Morinol C and (1S,2R)-morinol D were synthesized from (+)-(3R,4R)-4-(3,4-dimethoxyphenyl)-3-pivaloyloxymethyl-4-butanolide 4. On the other hand, (1S,2S)-morinol C and (1R,2S)-morinol D were synthesized from anti-aldol product 8.

Graphical abstract: Syntheses of the stereoisomers of neolignans morinol C and D

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Article information

DOI
https://doi.org/10.1039/B211801G
Article type
Paper
Submitted
04 Dec 2002
Accepted
12 Feb 2003
First published
12 Mar 2003

Org. Biomol. Chem., 2003,1, 1323-1329

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Syntheses of the stereoisomers of neolignans morinol C and D

S. Yamauchi and H. Uno, Org. Biomol. Chem., 2003, 1, 1323 DOI: 10.1039/B211801G

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