Issue 2, 2003
From the journal:

Mendeleev Communications

Unusually strong temperature dependence of 13C chemical shifts and degenerate conformational exchange in cyclobutenyl carbocations

Georgii E. Salnikov,*a   Alexander M. Genaeva  and  Victor I. Mamatyuka  

* Corresponding authors

a N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation, Prospekt Akademika Lavrent'eva, 9, Novosibirsk, Russian Federation
E-mail: sge@nmr.nioch.nsc.ru

Abstract

The unusually strong temperature dependence of 13C chemical shifts is observed in methyl-substituted cyclobutenyl carbocations because of a very low inversion barrier of a four-membered ring.

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Article information

DOI
https://doi.org/10.1070/MC2003v013n02ABEH001702
Article type
Paper
Submitted
19 Dec 2002

Mendeleev Commun., 2003,13, 48-49

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Unusually strong temperature dependence of 13C chemical shifts and degenerate conformational exchange in cyclobutenyl carbocations

G. E. Salnikov, A. M. Genaev and V. I. Mamatyuk, Mendeleev Commun., 2003, 13, 48 DOI: 10.1070/MC2003v013n02ABEH001702

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