Issue 2, 2003
From the journal:

Mendeleev Communications

1H NMR characterization of intermediates formed by the activation of zirconocenes with methylaluminoxane at high Al/Zr ratios

Evgenii P. Talsi,*a   Konstantin P. Bryliakov,a   Nina V. Semikolenova,a   Vladimir A. Zakharov,a   Martin Ystenesb  and  Erling Rytterc  

* Corresponding authors

a G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation, prospekt Akademika Lavrent'eva, 5, Novosibirsk, Russian Federation
E-mail: talsi@catalysis.nsk.su

b Department of Chemical Engineering, Norwegian Univeristy of Science and Technology, Trondheim, Norway, , Trondheim, Norway

c Statoil Research Centre, Trondheim, Norway, , Trondheim, Norway

Abstract

Cation-like intermediates formed by the activation of zirconocenes L2ZrCl2 [L2 are cyclopentadienyl (Cp), indenyl (Ind) and fluorenyl (Flu) ligands] with methylaluminoxane (MAO) at high Al/Zr ratios were characterised by 1H NMR spectroscopy.

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Article information

DOI
https://doi.org/10.1070/MC2003v013n02ABEH001689
Article type
Paper
Submitted
20 Nov 2002

Mendeleev Commun., 2003,13, 46-48

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1H NMR characterization of intermediates formed by the activation of zirconocenes with methylaluminoxane at high Al/Zr ratios

E. P. Talsi, K. P. Bryliakov, N. V. Semikolenova, V. A. Zakharov, M. Ystenes and E. Rytter, Mendeleev Commun., 2003, 13, 46 DOI: 10.1070/MC2003v013n02ABEH001689

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