Issue 11, 2003
From the journal:

Dalton Transactions

Preparation and structural characterization of a novel dicopper(ii) complex with a terminal hydroxide: a structural model of an active site in phosphohydrolases†

Hidekazu Arii,a   Yasuhiro Funahashi,a   Koichiro Jitsukawaa  and  Hideki Masuda*a  

* Corresponding authors

a Department of Applied Chemistry, Nagoya Institute of Technology, Showa-ku, Nagoya 466-8555, Japan
E-mail: masuda@ach.nitech.ac.jp

Abstract

As an intermediate model for active dinuclear metal sites in phosphohydrolases, a novel dicopper(II) complex with a terminal hydroxide has been prepared using a new dinucleating ligand with intramolecular hydrogen-bonding N–H sites and sterically hindered tert-butyl groups. It has been characterized by X-ray structure analysis, magnetic susceptibility, and ESR and electronic absorption spectroscopies.

Graphical abstract: Preparation and structural characterization of a novel dicopper(ii) complex with a terminal hydroxide: a structural model of an active site in phosphohydrolases

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Article information

DOI
https://doi.org/10.1039/B303787H
Article type
Communication
Submitted
04 Apr 2003
Accepted
25 Apr 2003
First published
06 May 2003

Dalton Trans., 2003, 2115-2116

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Preparation and structural characterization of a novel dicopper(II) complex with a terminal hydroxide: a structural model of an active site in phosphohydrolases

H. Arii, Y. Funahashi, K. Jitsukawa and H. Masuda, Dalton Trans., 2003, 2115 DOI: 10.1039/B303787H

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