Issue 1, 2003
From the journal:

Dalton Transactions

Assembly of a manganese(ii) pyridine-3,4-dicarboxylate polymeric network based on infinite Mn–O–C chains†

Wei Chen,a   Qi Yue,a   Cheng Chen,a   Hong-Ming Yuan,a   Wei Xu,a   Jie-Sheng Chen*a  and  Su-Ning Wangab  

* Corresponding authors

a State Key Lab of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130023, P. R. China
E-mail: chemcj@mail.jlu.edu.cn

b Department of Chemistry, Queen's University, Kingston, ON, K7L 3N6, Canada

Abstract

A unique metal–organic polymer Mn·PDB·H2O (H2PDB = pyridine-3,4-dicarboxylic acid), with weak antiferromagnetic interactions both between the manganese(II) centers of an infinite Mn–O–C chain and between the adjacent chains, has been synthesized by the hydrothermal reaction of Mn(CH3COO)2·4H2O with H2PDB; X-ray diffraction shows that the polymer possesses a one-dimensional rectangular channel built up from pyridine rings and pseudo-layers formed by infinite straight Mn–O–C chain building units.

Graphical abstract: Assembly of a manganese(ii) pyridine-3,4-dicarboxylate polymeric network based on infinite Mn–O–C chains

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Article information

DOI
https://doi.org/10.1039/B210462H
Article type
Communication
Submitted
24 Oct 2002
Accepted
18 Nov 2002
First published
28 Nov 2002

Dalton Trans., 2003, 28-30

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Assembly of a manganese(II) pyridine-3,4-dicarboxylate polymeric network based on infinite Mn–O–C chains

W. Chen, Q. Yue, C. Chen, H. Yuan, W. Xu, J. Chen and S. Wang, Dalton Trans., 2003, 28 DOI: 10.1039/B210462H

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