Issue 1, 2003
From the journal:

Dalton Transactions

An anionic silver(i) column containing a novel asymmetric double cage with embedded acetylenediide and unprecedented μ5-ligation of the nitrate ion†

Quan-Ming Wanga  and  Thomas C. W. Mak*a  

* Corresponding authors

a Department of Chemistry, The Chinese University of Hong Kong, Shatin, Hong Kong SAR, P. R. China
E-mail: tcwmak@cuhk.edu.hk

Abstract

The new triple salt (PhCH2NMe3)4[Ag17(C2)2(CF3CO2)16(NO3)(H2O)4] (1) features an asymmetric silver(I) double cage constructed from the edge-sharing of a triangulated dodecahedron and a monocapped square antiprism, and an anionic columnar structure is generated with an unprecedented μ5-ligation mode of the nitrate ion.

Graphical abstract: An anionic silver(i) column containing a novel asymmetric double cage with embedded acetylenediide and unprecedented μ5-ligation of the nitrate ion

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Article information

DOI
https://doi.org/10.1039/B210057F
Article type
Communication
Submitted
14 Oct 2002
Accepted
18 Nov 2002
First published
26 Nov 2002

Dalton Trans., 2003, 25-27

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An anionic silver(I) column containing a novel asymmetric double cage with embedded acetylenediide and unprecedented μ5-ligation of the nitrate ion

Q. Wang and T. C. W. Mak, Dalton Trans., 2003, 25 DOI: 10.1039/B210057F

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