Issue 24, 2003
From the journal:

Chemical Communications

Dehydropolymerization of arylsilanes catalyzed by a novel silylmolybdenum complex

Makoto Minato,*a   Takaomi Matsumoto,a   Miyuki Ichikawaa  and  Takashi Ito*a  

* Corresponding authors

a Department of Materials Chemistry, Graduate School of Engineering, Yokohama National University, 79-5, Tokiwadai, Hodogaya-ku, Yokohama, 240-8501, Japan
E-mail: minato@ynu.ac.jp
Fax: +81-45-339-3933
Tel: +81-45-339-3933

Abstract

A complex [MoH3{Si(Ph)[Ph2PCH2CH2P(Ph)C6H4-o]2}] (1) can act as single-component catalyst for dehydrogenative polymerization of ArSiH2R (Ar = Ph, p-tolyl, o-tolyl; R = H, Me) to (ArSiR)n: p- and o- tolylsilane produced the polymers of respectable molecular weights (Mw of 17300 and 6700 respectively) and polymerization of secondary silane, methylphenylsilane, gave a substantial molecular weight (Mw of 1750).

Graphical abstract: Dehydropolymerization of arylsilanes catalyzed by a novel silylmolybdenum complex

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/B310663M
Article type
Communication
Submitted
02 Sep 2003
Accepted
21 Oct 2003
First published
03 Nov 2003

Chem. Commun., 2003, 2968-2969

Permissions

Request permissions

Dehydropolymerization of arylsilanes catalyzed by a novel silylmolybdenum complex

M. Minato, T. Matsumoto, M. Ichikawa and T. Ito, Chem. Commun., 2003, 2968 DOI: 10.1039/B310663M

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements