Single crystals built from porous molecular networks can react with agents that penetrate the crystals, cleave fragments from the network, and thereby increase the volume available for guests, all without loss of crystallinity.
E. Le Fur, E. Demers, T. Maris and J. D. Wuest, Chem. Commun., 2003, 2966 DOI: 10.1039/B308355A
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